What is nuclear energy and how it is obtained


Both Molybdenum and Uranium Vital for Nuclear Reactors

Molybdenum plays a more vital role in thefinancial climates. The largest number
global nuclear renaissance than you mightproceeding through the proposed, planned or
suspect. Without the silvery white metal,construction phases will be located along
the world's energy infrastructure wouldcoastal areas to service the most populated
somewhat suffer. But, nuclear power plantsareas. The greatest numbers of new
would be set back at least two decades. Theconstructions are expected from China, India,
new high performance stainless steels (HPSS)Japan, Russia, South Korea and Japan (and
contain as much as 7.5 percent molybdenum andpossibly  the  United  States).
can add more than three times the life to the
world's  aging nuclear fleet condenser tubes.Existing reactors along coastal areas in
Asian countries presently breaks down as
During the early construction of nuclearfollows: Japan (57), South Korea (26), China
power plants, steam condensers relied uponand Taiwan (19) and India (11). Because these
copper base alloys - brass and copper nickelare the most prone to seawater or brackish
- for heat transfer capabilities. Thesecorrosion, they are also the likely
alloys have high coefficients of thermalcandidates for upgrading existing condenser
conductivity required in steam generation totubing to high alloy stainless steel. And
power nuclear reactor turbines. Buttheir new reactors are likely going to be
copper-alloyed tubes were being replaced tooconstructed along their coasts, requiring the
quickly - with an average life of eight yearssuper austenitic grades. As an aside, of the
- because of sulphide pitting. Hardest hitpreviously mentioned 190 nuclear power plants
were those reactors using polluted seawaterwhich had replaced their condensers with
to  cool  their  reactors.HPSS, 45 percent used fresh water as coolant.
Those plants chose the high alloy steel as a
Over the past 30 years ago, nuclear utilities'fail-safe' measure to prevent interrupted
slowly began turning to the super austeniticservice  or  a  potential  reactor  incident.
stainless steels as one way to make their
nuclear reactors last longer. The addition ofThe United Nations estimates that two-thirds
molybdenum, initially starting withof the planet's population will be living
percentage of less than four percent, helpedwith water stress by 2025. Global freshwater
increase the thermal conductivity lacking inscarcity may demand the use of brackish or
nickel, iron or steel. At nuclear stationsseawater as nuclear reactor coolant. To
which replaced the copper alloys with HPSSprevent the accompanying corrosion, the
condenser tubes, 57 percent rated the thermalhigher-percentage molybdenum alloy,
performance good and all but one rated itspecifically the 654 SMOÂ(R), could
normal. Molybdenum had helped overcome theemerge as the condenser tubing material of
thermal  hurdle.choice. Either the 254 SMOÂ(R) or the 654
would be utilized in desalination plants
A large number of the 190 nuclear reactors,required to overcome water shortages in the
which now utilize HPSS condenser tubes,hardest hit areas: North Africa, the Middle
reported an average life in excess of 18East  and  West  Asia.
years. The longest stainless steel condenser
installation has remained in service moreTypically, nuclear power plant condenser
than 26 years, according to a study donetubing requires approximately 520,000 feet of
several years ago. According to a reportstainless steel. According to the
published in 2000, more than 100 million feetInternational Molybdenum Association (IMOA),
of super-alloy stainless steel tubes havelarger reactors could utilize up to one
replaced  the  older,  copper-alloy  tubing.million feet of stainless steel. With the
higher molybdenum grades found in the super
Condensers are large heat exchangers used inalloys, new nuclear reactors could require
nuclear power plants. Condensers havetens of thousands of metric tons of
thousands of tubes horizontally mounted tomolybdenum.
condense and recover the steam passing
through turbines. Each low-pressure turbineBy comparison, nuclear waste containers
generally has a condenser, which alsoproposed for the Yucca Mountain nuclear waste
maintains a vacuum to optimize the turbine'srepository were forecast to consume about
efficiency.15,000 metric tons of moly. While this
project may or may not proceed as planned to
Water fouling deposits were cited as a majorthe construction phase, the Nuclear Energy
problem at many reactors, especially withInstitute (NEI) has proposed regionalized
condenser tubes where seawater orstorage  of  spent  fuel.
high-chloride brackish water was the coolant.
Pitting corrosion, tube sheet creviceShould comparably designed storage canisters
corrosion and galvanic corrosion put thebe utilized to 'temporarily' contain the
tubes at risk for leakage. Plugging, mud, ornuclear waste, it is likely molybdenum will
detritus accumulating in condenser tubesplay a key role. According to the U.S.
reduce  a  power  plant's  efficiency.Government's Energy Citation Database, as
published by the Department of Energy's
Utilities use cleaning systems with small,Office of Scientific and Technical
abrasive sponge-like balls to keep the tubesInformation, "Alloys with combined chromium
clean and test for tube defectives withplus molybdenum contents greater than 30
probing devices. Tube thinning and corrosionpercent were the most resistant to general
create the opportunity for tube leakage. Thisand local attack." This was the conclusion
can not be tolerated because chemicals suchreached after corrosion scouring tests were
as sodium and chlorides find their way intoperformed on stainless steel and nickel-based
the  reactor  vessel  or  steam  generator.alloys to immobilize high-level, radioactive
waste. Another aspect where
Upgrading the steam condenser tubing tohigh-percentage molybdenum stainless steel
stainless steel also plays a vital role inwould double up is with the expansion of
the 'power uprate' program utilities havenuclear desalination plants. In the past, and
used to increase generating capacity forin our publication, "Investing in the Great
existing reactors as we recently discussed.Uranium Bull Market," we have discussed the
The more advanced uprate program could add uprise of nuclear desalination across those
to 20-percent capacity to existing U.S.coastal areas, requiring far more freshwater
nuclear  reactors.than can possibly be transported through
other means. The World Nuclear Association
Different  Molybdenum  Alloys(WNA) has reported of numerous such
desalination  projects  in  progress.
There are several HPSS manufacturers for
nuclear reactor condensers. The mostWill  The  Energy  Bull Have Sufficient Moly?
prominent in the nuclear sector include
Pennsylvania-based ATI Allegheny Ludlum andFrom nearly every energy project - oil, gas,
Finland's Outokumpu. Each offers austeniticcoal and nuclear, and for water, molybdenum
steels with chromium and nickel compositiondemand will continue increasing. Super
of between 20 and 25 percent for each alloyaustenitic grades demand a higher moly
and a range of 6.2 to 7.5 percent molybdenum.content to combat corrosion and provide
reliability of service. Of course, there will
In a paper presented by Jan Olsson of Avestabe substitution in the face of future supply
Sheffield (before the company was acquired byshortfalls. In some instances, there are
Outokumpu), he highlighted the results ofreports the Russians have substituted
tests performed on the new super-austeniticvanadium for molybdenum in some of their oil
stainless steel, 654 SMOÂ(R). Metalsand gas pipelines to conserve on moly
comprising this brand include 25-percentconsumption. ATI Allegheny Ludlum has argued
chromium, 22-percent nickel and 7.5-percentfor the substitution of two-percent manganese
molybdenum. To increase pitting resistance,for every percent of nickel, but in the lower
the manufacturers added up to 0.5-percentgrade austenitic groups which do not demand
nitrogen and three-percent manganese (forthe corrosion resistance of energy projects.
make  the  nitrogen  more  soluble).While reviewing the anticipated new projects
from the molybdenum mining sector, we foresee
As with all pioneering developments - andthe high probability of supply inadequacy.
remember that R & D breakthroughs have takenAside from China Moly's Sandaozhuang
place over a two-decade-plus period,molybdenum mine, which the company hopes
manufacturers have re-designed theircould produce 28,000 tonnes of molybdenum
metallurgical composition to find the mostconcentrate this year and perhaps grow by
encouraging percentages of nickel, chromium,another 17 percent the following year, there
molybdenum and nitrogen. The earlieris a paucity of new molybdenum projects
stainless steels relied on higher nickelcoming  fully  online  before  2009.
content and lesser percentages of chromium
and  molybdenum.Based upon China's voracious appetite for
molybdenum - one research firm estimated
At first, conventional austenitic grades,compounded annual growth rate over the
such as 316L, or high chromium-ferriticprevious five years at 17 percent, whatever
grades, were utilized. Pitting struck downexcess moly production comes from China
widespread use of the 316L series and wasMoly's mining efforts could very well be
replaced by higher alloy steels. For example,domestically  consumed.
others, such as the 254 SMOÂ(R) stainless
steel, began aggressively replacing theFuture North American molybdenum producers
copper alloy tubes and in some cases the 316Lmay need to ramp up their projects to meet
series. The 254 is comprised of 20-percentthe growing demand. During 2006, demand grew
chromium, 18-percent nickel, 6.2-percentabove the historical norm of four percent;
molybdenum and 0.20-percent nitrogen. It hasmost of the consumption came from China. This
also offered a high level of corrosionis unlikely to stagnate or decrease, and
resistance at desalination plants withoutcould interfere with North American and
becoming  cost-prohibitive.European  consumption  of  molybdenum.
The most significant breakthrough came afterOnly one company is scheduled to commence
various stainless steels were tested atmolybdenum mining in 2007, Roca Mines.
Scandinavian coastal reactors. In the AvestaBecause the company is limited to a
paper, the failures of each lesser austeniticsmall-mining permit, anticipated production
grade were checked off. Significantcould not exceed three million pounds. By
deficiencies included insufficient stresslate 2008, or early 2009, Adanac Molybdenum
corrosion cracking resistance and resistancehopes to commence its start-up efforts to
to natural seawater. Even titanium tubing wasreach eight-figure moly production. Later,
used as an interim measure because itBlue Pearl Mining hopes to commence
increased total heat transfer by 17 percent,high-grade molybdenum mining at the Davidson
but the metal failed to stand up to highdeposit in British Columbia. Around this
velocity steam and suffered 'water droplettime, the Climax molybdenum mine could
erosion.'re-open and begin production in Colorado.
Moly Mines hopes to begin production at the
According to the study, "The only alloy fullycompany's Spinifex project. Possibly, before
resistant to all test conditions was 654the decade ends, Idaho General might commence
SMOÂ(R)." The results at nuclear poweroperations in Nevada. Perhaps before those 48
plants in Finland and Sweden, along thenuclear reactors come online, US Energy's Mt.
Baltic Sea, were astonishing! Four importantEmmons  deposit  may  be  mined  in Colorado.
conclusions about this super alloy were
reached  after  the  testing.Many of these projects are subject to
environmental permitting and/or financing,
· Its corrosion resistance could copeputting any material amount of forecasted
with the hostile environments existing insidesupply in jeopardy. And this comes at a time
condenser tubes of desalination plants andwhen some experts believe byproduct
power  plants.molybdenum production at copper mines could
be constrained. There are many conditional
· Its corrosion resistance was goodrequirements which do not necessarily
enough to cop with many other hostile brineguarantee a reliable supply from the new
and  seawater  environments.breed of primary moly producers. We have
witnessed comparable obstacles in the uranium
· Its erosion resistance wassector, which has since been accompanied by a
advantageous where it was exposed to highhyperbolic  price  rally  in  this  metal.
velocity  streams.
There could come a point in the molybdenum
· There was no concern about its heatsector where the silvery white metal could
transfer  characteristics.mimic such a breakout scenario. Nearly three
years ago, featured a forecast of US$100
Nuclear  Consumption  of  Molybdenumpound uranium. No one believed that
prediction at the time. On Friday, TradeTech
About 48 nuclear reactors are reportedlyannounced  a  spot  price  of  US$113/pound.
scheduled for construction by 2013. It may be
possible that up to 100 could be constructedCOPYRIGHT© 2007 by StockInterview,
by 2020, depending upon political andInc. ALL RIGHTS RESERVED.



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